Pretty rare for a Main Event to be a non-title match, though.
Was 'Taker v. Mankind Hell In The Cell the ME on that card? That'd be up there as I'm pretty sure there wasn't a title on the line.
World War 3 '96 had a good finish. Came down to (if I remember right) Luger, Savage (the previous years winner), Giant, Nash, Hall & Syxx. Basically 5-on-1. Luger getting booked to nearly pull off the win was pretty good. The last 2 minutes or so of him eliminating one after the other before getting tossed by a recovered (from The Torture Rack) Giant on a double elimination was pretty hype. I don't remember shit else from the match, though. Split screen, 3 rings...a lot to try and concentrate on.
Sting v. Flair, last match of WCW, the penultimate "main event".